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Effect: This weapon oozes with magical poisons from a dozen esoteric sources. Occasionally, these toxins will erupt on your target, unleashing a vile fog that will dissolve your foes with acid, and will additionally deal constitution damage to enemies whom are not immune to poison. Weak foes may be killed outright by this Toxic Cloud.
Found on: (4) Toxic items:

Originally Posted by (former developer) Feather_of_Sun Source

Toxic mutation is an on-hit proc that creates an AoE damage over time cloud, dealing significant acid damage over 10 seconds. It does damage enemies who are immune to poison. The constitution damage portion of it is the only part that is blocked by poison immunity.